Please check your email address / username and password and try again. Hydrogen may also be added to reactor coolant to remove oxygen from reactor coolant systems. metals, differing only in that at low temperatures and relatively high strain rates complete recovery in ductility was not achieved. Austempered iron is also susceptible, though austempered steel (and possibly other austempered metals) display increased resistance to hydrogen embrittlement. Hydrogen embrittles a variety of substances including steel, aluminium (at high temperatures only ), and titanium. ©NACE International. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and load-bearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. If stress induces cracking under these conditions, the path is transgranular. The methane gas is not mobile and collects in small voids along the grain boundaries where it builds up enormous pressures that initiate cracks. The cracking of martensitic and precipitation hardened steel alloys is believed to be a form of hydrogen stress corrosion cracking that results from the entry into the metal of a portion of the atomic hydrogen that is produced in the following corrosion reaction. Presently this phenomenon is not completely understood and hydrogen embrittlement detection, in particular, seems to be one of the most difficult aspects of the problem. If the presence of hydrogen sulfide causes entry of hydrogen into the component, the cracking phenomenon is often termed “sulphide stress cracking (SSC)”. Type 310 stainless steel in thin sections was embrittled by hydrogen. Hydrogen embrittlement does not affect all metallic materials equally. All rights reserved. Recent research activities on hydrogen embrittlement, especially Hydrogen Environment Embrittlement (HEE) susceptibility of stainless steels in highly pressurized gaseous hydrogen environments were reviewed from the viewpoints of effects of chemical compositions, hydrogen … doi: https://doi.org/10.5006/0010-9312-21.2.53. Type 310 stainless steel in thin sections was embrittled by hydrogen. At high temperatures, the absorbed hydrogen tends to gather in the grain boundaries and stress-induced cracking is then intergranular. The activation energy for recovery in ductility, determined by aging at several temperatures, was 10,900 cal/mole. CORROSION 1 February 1965; 21 (2): 53–56. In this situation, cracking failures can often be thought of as a type of stress corrosion cracking. Hydrogen Embrittlement of Stainless Steel. Hydrogen diffuses along the grain boundaries and combines with the carbon, which is alloyed with the iron, to form methane gas. You could not be signed in. Hydrogen embrittlement is a primary reason that the reactor coolant is maintained at a neutral or basic pH in plants without aluminum components. At normal room temperatures, the hydrogen atoms are absorbed into the metal lattice and diffused through the grains, tending to gather at inclusions or other lattice defects. The temperature and strain rate dependence of this embrittlement was almost analogous to that well-established for hydrogenated body-centered cubic (b.c.c.) This is a type of deterioration which can be linked to corrosion and corrosion-control processes. Hydrogen embrittlement occurs in a number of forms but the common features are an applied tensile stress and hydrogen dissolved in the metal. Hydrogen entry, the obvious pre-requisite of embrittlement, can be facilitated in a number of ways summarized below: (Defence Standard 03-30, October 2000). (1990) High voltage electron microscopy studies of grain boundary effects on hydrogen embrittlement of stainless steel. If the metal is under a high tensile stress, brittle failure can occur. Hydrogen diffuses along the grain boundaries and combines with the carbon, which is alloyed with the iron, to form methane gas. This website uses cookies to ensure you get the best experience on our website. Search for other works by this author on: © 1965 National Association of Corrosion Engineers. Materials Science and Engineering: A 128:1, 91-97. Hydrogen embrittlement is not a permanent condition. M. B. WHITEMAN, A. R. TROIANO; Hydrogen Embrittlement Of Austenitic Stainless Steel. How to Prevent Hydrogen Embrittlement.